The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy / t-C4H9O2,(CH3)3CO2 / Lightfoot(1990)_298K_210-280nm(resc,L-rev)

DATAFILE: t-C4H9O2,(CH3)3CO2_Lightfoot(1990)_298K_210-280nm(resc,L-rev).txt
NAME: 1,1,1-dimethylethylperoxy radical, tert-butylperoxy radical
FORMULA: t-C4H9O2,(CH3)3CO2
AUTHOR(YEAR): Lightfoot(1990)
T: 298K
λ: 210-280nm(resc,L-rev)
BIBLIOGRAPHY: P.D. Lightfoot, P. Roussel, B. Veyret, and R. Lesclaux, "Flash photolysis study of the spectra and self-reactions of neopentylperoxy and t-butylperoxy radicals", J. Chem.Soc. Faraday Trans. 86, 2927-2936 (1990); DOI: 10.1039/FT9908602927
COMMENTS: L-rev = Lightfoot review

The measured absorption cross sections were rescaled by

P.D. Lightfoot, R.A. Cox, J.N. Crowley, M. Destriau, G.D. Hayman, M.E. Jenkin, G.K. Moortgat, and F. Zabel, "Organic peroxy radicals: Kinetics, spectroscopy and tropospheric chemistry," Atmos. Environ. 26A, 1805-1961 (1992); DOI: 10.1016/0960-1686(92)90423-I,

using the factor 4.58/4.80

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